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814552 Sodium hydride suspension

Sodium hydride suspension (60% suspension in paraffin oil) for synthesis. CAS No. 7646-69-7, EC Number 231-587-3.

Sodium hydride suspension MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
CAS #: 7646-69-7 EC Number: 231-587-3 Molar Mass: 24.0 g/mol Chemical Formula: NaH Hill Formula: HNa
814552
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Overview

Replacement Information

Key Specifications Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
7646-69-7231-587-3HNaNaH24.0 g/mol

Products

Catalog NumberPackaging Qty/Pack
8145520100 Glass bottle 100 g
Description
Catalogue Number814552
References
Product Information
CAS number7646-69-7
EC index number001-003-00-X
EC number231-587-3
Hill FormulaHNa
Chemical formulaNaH
Molar Mass24.0 g/mol
HS Code3824 99 79
Quality LevelMQ200
Applications
ApplicationSodium hydride suspension (60% suspension in paraffin oil) for synthesis. CAS No. 7646-69-7, EC Number 231-587-3.
Biological Information
Physicochemical Information
Density0.92 g/cm3 (20 °C)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H260: In contact with water releases flammable gases which may ignite spontaneously.
H290: May be corrosive to metals.
H304: May be fatal if swallowed and enters airways.
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)P231 + P232: Handle and store contents under inert gas. Protect from moisture.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P402 + P404: Store in a dry place. Store in a closed container.
Signal WordDanger
Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 2 obviously hazardous to water
Disposal26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Categories of dangerhighly flammable, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1427 , 4.3, I
Declaration (transport by air) IATA-DGRUN 1427 , 4.3, I
Declaration (transport by sea) IMDG-CodeUN 1427 , 4.3, I
Supplemental Information
Specifications
Assay (by gasvolumetry)≥ 57.0 %
Global Trade Item Number
Catalog Number GTIN
8145520100 04022536417110

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Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Organometallic Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents