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807246 Sigma-Aldrich1,4-Phenylenediamine

1,4-Phenylenediamine for synthesis. CAS 106-50-3, pH 9 (50 g/l, H₂O, 20 °C).

1,4-Phenylenediamine MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

SDS
CoA

CAS #: 106-50-3 EC Number: 203-404-7 Molar Mass: 108.14 g/mol Hill Formula: C₆H₈N₂

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Overview

Replacement Information

Key Specifications Table

CAS #	EC Number	Hill Formula	Molar Mass
106-50-3	203-404-7	C₆H₈N₂	108.14 g/mol

Pricing & Availability

Catalog Number	Availability	Packaging	Qty/Pack	Price	Quantity
8072460005	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Glass bottle	5 g	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites
8072460250	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Glass bottle	250 g	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites
8072461000	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Glass bottle	1 kg	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites
8072469025	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Plastic drum	25 kg	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites

Description
Catalogue Number	807246

References

Product Information
CAS number	106-50-3
EC index number	612-028-00-6
EC number	203-404-7
Hill Formula	C₆H₈N₂
Molar Mass	108.14 g/mol
HS Code	2921 51 19
Structure formula Image
Quality Level	MQ200

Applications
Application	1,4-Phenylenediamine for synthesis. CAS 106-50-3, pH 9 (50 g/l, H₂O, 20 °C).

Biological Information

Physicochemical Information
Boiling point	267 °C (1013 hPa)
Density	0.726 g/cm3 (22 °C)
Flash point	110 °C
Ignition temperature	567 °C
Melting Point	139 - 141 °C
pH value	9 (50 g/l, H₂O, 20 °C)
Vapor pressure	1.44 hPa (100 °C)
Bulk density	600 kg/m3
Solubility	47 g/l

Dimensions

Materials Information

Toxicological Information
LD 50 oral	LD50 Rat 80 mg/kg
LD 50 dermal	LD50 Rabbit > 7940 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H370: Causes damage to organs if swallowed. H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s)	P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302 + P352 + P312: IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal Word	Danger
RTECS	SS8050000
Storage class	6.1D Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3 highly hazardous to water

Safety Information
Categories of danger	toxic, irritant, sensitizing, dangerous for the environment

Product Usage Statements

Storage and Shipping Information
Storage	Store below +30°C.

Packaging Information

Transport Information
Declaration (railroad and road) ADR, RID	UN 1673 , 6.1, III
Declaration (transport by air) IATA-DGR	UN 1673 , 6.1, III
Declaration (transport by sea) IMDG-Code	UN 1673 , 6.1, III

Supplemental Information

Specifications
Assay (GC, area%)	≥ 98.0 % (a/a)
Identity (IR)	passes test

Global Trade Item Number
Catalog Number	GTIN
8072460005	04022536394381
8072460250	04022536394398
8072461000	04022536394404
8072469025	04022536394411

Documentation

1,4-Phenylenediamine SDS

Title
Safety Data Sheet (SDS)

1,4-Phenylenediamine Certificates of Analysis

Product Number	Packaging	Specification	Lot Number
8072460005	Glass bottle	PDF Specification Document	Enter Lot Number
8072460250	Glass bottle	PDF Specification Document	Enter Lot Number
8072461000	Glass bottle	PDF Specification Document	Enter Lot Number
8072469025	Plastic drum	PDF Specification Document	Enter Lot Number

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