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805894 Sigma-Aldrich4-Methylmorpholine

4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50 g/l, H₂O, 20 °C).

4-Methylmorpholine MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

SDS
CoA

Synonyms: NMM, N-Methylmorpholine

CAS #: 109-02-4 EC Number: 203-640-0 Molar Mass: 101.15 g/mol Hill Formula: C₅H₁₁NO

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Overview

Replacement Information

Key Specifications Table

CAS #	EC Number	Hill Formula	Molar Mass
109-02-4	203-640-0	C₅H₁₁NO	101.15 g/mol

Pricing & Availability

Catalog Number	Availability	Packaging	Qty/Pack	Price	Quantity
8058940005	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Glass bottle	5 ml	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites
8058940250	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Glass bottle	250 ml	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites
8058941000	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Glass bottle	1 l	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites
8058942500	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Glass bottle	2.5 l	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites
8058949025	Retrieving availability... — Limited Availability Stocked Discontinued Limited Quantities Available Available Login to See Inventory Stocked Limited Availability Stocked Remaining : Will advise Remaining : Will advise Will advise Contact Customer Service Contact Customer Service Contact Customer Service Contact Customer Service	Barrel PE/met	25 kg	Retrieving price... Price could not be retrieved Minimum Quantity is a multiple of Maximum Quantity is Upon Order Completion More Information You Saved () — Request Pricing Login to See Your Pricing	Check Availability —	Add To Favorites Add To Favorites Added To My Favorites

Description
Catalogue Number	805894
Synonyms	NMM, N-Methylmorpholine

References

Product Information
CAS number	109-02-4
EC number	203-640-0
Hill Formula	C₅H₁₁NO
Molar Mass	101.15 g/mol
HS Code	2934 99 90
Structure formula Image
Quality Level	MQ200

Applications
Application	4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50 g/l, H₂O, 20 °C).

Biological Information

Physicochemical Information
Boiling point	112 - 114 °C
Density	0.92 g/cm3 (20 °C)
Explosion limit	2.2 - 11.8 %(V)
Flash point	12 °C DIN 51755 Part 1
Ignition temperature	165 °C DIN 51794
Melting Point	-66 °C
pH value	10.6 (50 g/l, H₂O, 20 °C)
Vapor pressure	23.5 hPa (20 °C)

Dimensions

Materials Information

Toxicological Information
LD 50 oral	LD50 Rat 1960 mg/kg
LD 50 dermal	LD50 Rabbit 1240 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H225: Highly flammable liquid and vapour. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)	P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal Word	Danger
RTECS	QE5775000
Storage class	3 Flammable liquids
WGK	WGK 1 slightly hazardous to water
Disposal	1 Strongly contaminated halogen-free organic solvents: container A.

Safety Information
Categories of danger	highly flammable, harmful, corrosive

Product Usage Statements

Storage and Shipping Information
Storage	Store below +30°C.

Packaging Information

Transport Information
Declaration (railroad and road) ADR, RID	UN 2535 , 3 (8), II
Declaration (transport by air) IATA-DGR	UN 2535 , 3 (8), II
Declaration (transport by sea) IMDG-Code	UN 2535 , 3 (8), II

Supplemental Information

Specifications
Color (visual)	colorless
Appearance of substance (visual)	clear
Assay (GC, area%)	≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C)	0.917 - 0.918
Identity (IR)	passes test

Global Trade Item Number
Catalog Number	GTIN
8058940005	04022536388083
8058940250	04022536388090
8058941000	04022536388106
8058942500	04022536748092
8058949025	04022536868257

Documentation

4-Methylmorpholine SDS

Title
Safety Data Sheet (SDS)

4-Methylmorpholine Certificates of Analysis

Product Number	Packaging	Specification	Lot Number
8058940005	Glass bottle	PDF Specification Document	Enter Lot Number
8058940250	Glass bottle	PDF Specification Document	Enter Lot Number
8058941000	Glass bottle	PDF Specification Document	Enter Lot Number
8058942500	Glass bottle	PDF Specification Document	Enter Lot Number
8058949025	Barrel PE/met	PDF Specification Document	Enter Lot Number

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Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines

Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines

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